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An open source live chat is essentially and excellent complement to almost any website.  It always enables site visitors to communicate in real-time concerning the site’s subject, providing businesses an great advantage of understanding in real-time what their site visitors like or don’t like regarding their products or services.
Whether you are a website owner or a company holder, for both of you I’ve compiled 25 most useful chat widgets and chat client tools to use for your own website or just use some of them to communicate with your workers.

Google Talk chatback badge

A Google Talk chatback badge will let visitors to your web page chat with you. They’ll be able to chat with you whenever you’re signed in to Google Talk as multyshades@gmail.com..

Yahoo Messenger Pingbox

Chat privately with visitors on your social network profiles, blog, or website through Yahoo! Messenger..

Rumbletalk

RumbleTalk provides a live customizable chat widget that can be added to any web page..

Plugoo

Let your website visitors chat with you while you’re online in your messenger..

Meebome

Meebo me is designed for anyone with a home on the web. If you’ve got a web page where you’d like to communicate with your visitors, meebo me allows you to see the people who are visiting your web page and chat with them!

Tokbox

Weave face-to-face communication into your site with our flexible API or a simple, plug-n-play app..

Shoutmix

Add live chat capabilities to your website today. Get instant feedback and great user interaction with our shoutbox chat widget..

Mibbit

If you’d like to have webchat on your own website, you could use a Java applet that requires a 3rd-party download or you could use Mibbit, which requires no special download at all!

Digsby

Manage all your existing IM, email, and social network accounts from one easy to use application..

AJAX Chat

AJAX Chat is a free and fully customizable open source web chat software implemented in JavaScript, PHP and MySQL. Sound support is implemented using Flash, Socket support using Flash on client-side and Ruby on server-side.

PHP Free Chat

phpFreeChat is a free, simple to install, fast, customizable and multi languages chat that uses a simple filesystem for message and nickname storage.

Woopra

Live Chat Support Initiate chat with your visitors Respond to their chat requests.

Cbox

Get a Cbox and add a new dimension of interaction to your website or blog. Cbox is a unique chat and messaging application that brings the best features of traditional chat and tagging systems to the social web. And the best part – Cbox Basic is completely free.